Chelsea were defeated over two legs in last season's semi-finals by the Scousers.
Chelsea will also face Belgium side Andrelecht and Spanish side Real Betis from Serville.
The full draw is as follows:
REAL MADRID - LYON -OLYMPIARKOS - ROSENBERG
ARSENAL - AJAX - SPARTA PRAGUE- THUN
AC MILAN - PSV - SHALKE - FENERBACHE
MAN UTD - VILLERIEAL - LILLE - BENFICA
INTER MILAN - PORTO - RANGERS - BRATSLAVIA
BARCELONA - PANATHANIKOS - WERDER BREMAN - UDINESE
BAYERN MUNICH - JUVENTUS - BRUGGE - RAPID VIENNA